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Electrical conductivity explained
Syllabus VWO: Bonding and properties
Explain conduction using the correct charged particles and their mobility.
Charge must be able to move
In solid sodium chloride, charged ions occupy fixed positions in a lattice. When melted or dissolved, the ions can move. The presence of ions alone is therefore not enough.
Metals are different
Mobile electrons carry charge in copper. In a sugar solution the dissolved particles are neutral molecules. In this classroom model its conduction is negligible compared with a salt solution.
Why does molten NaCl conduct whereas solid NaCl does not?
- Both contain Na⁺ and Cl⁻ ions.
- In the solid they occupy fixed lattice positions; in the melt they can move.
In the melt, ions transport electric charge.